e-Article
Part 1, Synthesis and thermolysis of cyclopentadienyl and pentamethylcyclopentadienyl molybdenum dioxo alkoxides; Part 2, Structural characterization of polysilicate intermediates formed during sol-gel polymerization
Document Type
Technical Report
Author
Source
Other Information: Thesis (Ph.D.)
Subject
Language
English
Abstract
Part 1. The molybdenum(VI) dioxo alkoxides ({eta}{sup 5} {minus} C{sub 5}H{sub 5}) MoO{sub 2}(OR) (R = CH{sub 2}CH{sub 3}, CH)(CH{sub 3})({sub 2}) and ({eta}{sup 5} {minus} C{sub 5})(CH{sub 3})({sub 5})MoO{sub 2}(OR) (R = CH{sub 3}, CH{sub 2}CH{sub 3}, CH(CH{sub 3}{sub 2})) have been prepared and characterized. Part 2. The principal mono- through hexasilicate structural isomers formed by hydrolysis of methanolic tetramethylorthosilicate in the presence of HCl have been structurally assigned and quantitatively determined.