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Crystallization in “Tarassaco” Italian honey studied by DSC
Document Type
Article
Source
Food Chemistry. Sep2010, Vol. 122 Issue 2, p410-415. 6p.
Subject
*CRYSTALLIZATION
*HONEY
*NATURAL sweeteners
*COMMON dandelion
*AMORPHOUS substances
*ENTHALPY
*GLASS transition temperature
*CALORIMETRY
Language
ISSN
0308-8146
Abstract
Abstract: The degree and rates of crystallization in honey stored at 5°C, 10°C, 15°C, 20°C and 25°C were examined, with reference to rate enhancing and rate limiting factors of both thermodynamic and kinetic nature. Crystals of “Tarassaco” honey (from Taraxacum officinale Weber), mainly glucose monohydrate, were separated and purified from the residual amorphous phase and the enthalpy of melting was determined by DSC. The melting enthalpy resulted 108.39±6.16Jg−1. The crystallization rates were 0.659, 0.755, 0.861, 0.815 and at the cited temperatures. The water activity (a w) increased from 0.593 in the liquid honey to 0.658, 0.652, 0.647, 0.639 and 0.640 after 222 days storage. The relationships among crystallization, supersaturation, glass transition temperatures (T g), melting temperatures (T m), difference (T–T g), viscosity and a w are discussed. [Copyright &y& Elsevier]