학술논문

Novel Aspects in the Preparation of Phorone
Document Type
Article
Source
Zeitschrift für Naturforschung B; April 1978, Vol. 33 Issue: 4 p454-460, 7p
Subject
Language
ISSN
09320776; 18657117
Abstract
The condensation of acetone using anhydrous hydrogen chloride results after three weeks at room temperature, in a 15% yield of phorone (4) and a 75% yield of mesityl oxide (5). In the presence of one weight percent of the Lewis acid, aluminium chloride, the yield of 4 is increased to 39%. An increase in the amount of the Lewis acid, aluminium chloride, to ten weight percent results in a 22% yield of phorone (4) and a 68% yield of mesityl oxide (5). In the presence of one hundred weight percent of aluminium chloride,