학술논문
Fast, long-range electron-transfer reactions of a ‘blue’ copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer
Document Type
Article
Author
Source
Chemical Communications; 2004, Vol. 2004 Issue: 3 p316-317, 2p
Subject
Language
ISSN
13597345; 1364548X
Abstract
A self-assembled monolayer SAM, formed by the insitusaponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer ET the exchange rate at zero driving force exceeds 1600 s−1 with adsorbed molecules of the ‘blue’ copper protein, azurin, over a distance exceeding 15 .