학술논문

Method of making catalyst and catalyst precursor containing vanadium and antimony
Document Type
Patent
Author
Source
Patent File Date: 14 Nov 1988
Subject
02 PETROLEUM CATALYSTS
CHEMICAL PREPARATION
ANTIMONY COMPOUNDS
AQUEOUS SOLUTIONS
CHEMICAL COMPOSITION
GELS
OXIDATION
VANADIUM OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
COLLOIDS
DISPERSIONS
MIXTURES
OXIDES
OXYGEN COMPOUNDS
SOLUTIONS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
VANADIUM COMPOUNDS 020500* -- Petroleum-- Products & By-Products
Language
English
Abstract
This patent describes a method of making a catalyst precursor having vanadium and antimony in oxide form in the atomic ratio of Sb to V in the range from 0.8 to 4. It comprises aging in an aqueous solution containing the monoperoxovanadium ion, VO(O{sub 2}){sub +}, until a vanadium-containing sol or gel is formed, and reacting the vanadium while in the aqueous sol or gel form, with an antimony compound which contains Sb having a valence of 3, thereby reducing the average valence of the vanadium to less than 5 and oxidizing antimony to a valence state of 5.