학술논문

Preparation and multifaceted characterization and optoelectronic potential of Cu/CuO/Cu2O nanoplates in a PVC/PE matrix
Document Type
Original Paper
Source
Journal of Materials Science: Materials in Electronics. 35(3)
Subject
Language
English
ISSN
0957-4522
1573-482X
Abstract
In this study, we thoroughly investigate the physicochemical properties of Cu/CuO/Cu2O nanoplates synthesized in distinct plate-like structures. These nanoplates were incorporated into a polymer matrix (PVC/PE) at varying concentrations (0, 1, 2, and 3%). Employing various analytical techniques, including X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR), optical absorption, and alternating current (AC) conductivity measurements, we unravel the structural, morphological, molecular, optical, and electrical characteristics of these nanostructures. The results showcase the potential of these nanocomposites for optoelectronic device applications by exhibiting tunable optical bandgaps and frequency-dependent dielectric properties. In particular, the observed redshift in the absorption spectrum and modulation of the direct bandgap with increasing nanoplate content underscores their application in spectral selectivity and light harvesting. Furthermore, the transition from insulating to conducting behavior upon percolation signifies their utility in transparent conductive coatings. This study provides fundamental insights into the structure–property relationships of Cu/CuO/Cu2O nanoplate polymer nanocomposites for tailored optoelectronic applications.