학술논문

Degradation of organic pollutants and characteristics of activated sludge in an anaerobic/anoxic/oxic reactor treating chemical industrial wastewater
Document Type
article
Source
Brazilian Journal of Chemical Engineering. September 2014 31(3)
Subject
Anaerobic/anoxic/oxic process
Chemical industrial wastewater
Fe(III) accumulation
Organic matter classification
Hydraulic retention time
Language
English
ISSN
0104-6632
Abstract
A laboratory-scale anaerobic/anoxic/oxic system operated at the hydraulic retention times (HRT) of 20, 40, and 60 h with mixed liquor suspended solids (MLSS) concentrations of 3 g/L and 6 g/L was considered for treating chemical industrial wastewater rich in complex organic compounds and total dissolved solids. Extending the HRT and increasing the MLSS concentration resulted in higher removal efficiency for chemical oxygen demand at 72%. Organic compounds in wastewater could be classified into easily-removed and refractory compounds during treatment. The easily-removed compounds consisted primarily of ethers, alcohols, and aldehydes, whereas the refractory compounds included mainly oxygen-containing heterocyclic and benzene-containing compounds. Results from energy-dispersive X-ray spectroscopy showed that several metal ions accumulated in activated sludge, particularly Fe(III). Fe accumulated mainly on the surface of sludge floc pellets and resulted in the compactness of activated sludge, which caused the values of mixed liquor volatile suspended solids /MLSS and sludge volume index to decrease.