학술논문

홀뮴 도핑된 TiO2를 이용한 광전기화학 수소 제조
Photoelectrochemical Hydrogen Production with Holmium-doped TiO2
Document Type
Article
Source
한국수소및신에너지학회논문집, 34(5), pp.413-420 Oct, 2023
Subject
기계공학
Language
한국어
ISSN
2288-7407
1738-7264
Abstract
Holmium-doped TiO2 nanotubes (Ho-TNTs) were manufactured through anodization treatment and electrochemical deposition, and optimization experiments were conducted using various Holmium doping concentrations and time as variables. Surface as well as electrochemical characteristics were analyzed to study the prepared photocatalysts. Ho-TNTs were found to exist only in anatase phase through X-ray diffraction analysis. Ho-TNTs with 0.01 wt% 100 seconds shows a photocurrent density of 3.788 mA/cm2 and an effective photo- conversion efficiency (PCE) of 4.30%, which is more efficient than pure TiO2 nanotubes (pure-TNTs) (at bias potential 1.5 V vs. Hg/HgO). The photocatalytic activity of the aforementioned Ho-TNTs for hydrogen production was evaluated with the result of -29.20 μmol/h·cm2.