학술논문
A novel hexaaquacopper (II) complex: [3+3] distorted octahedral coordination and inorganic-organic interface
Document Type
Report
Source
Inorganic Chemistry Communications. July, 2005, Vol. 8 Issue 7, p647, 4 p.
Subject
Language
English
ISSN
1387-7003
Abstract
To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/j.inoche.2005.04.013 Byline: Lin-Fang Jia (a), Wen-Fu Fu (a)(b), Ming-Ming Yu (a), Qian-Yong Cao (a), Jun-Feng Zhang (a), Qi Yin (b) Keywords: Hexaaquacopper (II) complex; [3+3] coordination; Inorganic-organic interface; Hydrogen bond Abstract: A novel hexaaquacopper (II) complex Cu(H.sub.2O).sub.6(OPCy.sub.3).sub.6(BF.sub.4).sub.2 (OPCy.sub.3 =tricyclohexylphosphine oxygen) with an inorganic-organic interface through hydrogen bonding was synthesized and characterized. [3+3] coordination being different from that of [4+2] or [2+2+2] is reported. Author Affiliation: (a) Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, 5151 Group, Datun Road, No. 3, Beijing 100101, China (b) College of Chemistry and Chemical Engineering, Yunnan Normal University, Kunming 650092, China Article History: Received 19 January 2005; Accepted 22 April 2005