학술논문

Spatial Modulation of Vibrational and Luminescence Properties of Monolayer MoS₂ Using a GaAs Nanowire Array
Document Type
Periodical
Source
IEEE Journal of Quantum Electronics IEEE J. Quantum Electron. Quantum Electronics, IEEE Journal of. 58(4):1-8 Aug, 2022
Subject
Engineered Materials, Dielectrics and Plasmas
Photonics and Electrooptics
Optical imaging
Substrates
Gallium arsenide
Strain
Scanning electron microscopy
Optical sensors
Spectroscopy
Nanowires
photoluminescence
Raman spectroscopy
transition-metal dichalcogenides
Language
ISSN
0018-9197
1558-1713
Abstract
The integration of transition-metal dichalcogenides (TMDs) with non-planar substrates such as nanopillars provides a way to spatially modify the optical properties mainly through the localized strain. Similar studies to date have utilized insulating SiO 2 nanopillars. Here, we combine monolayer MoS 2 with free standing GaAs nanowires (NWs), in views of coupling their semiconducting properties. We find that monolayer MoS 2 exhibits three different configurations: pierced, wrapped and tent-like. We demonstrate how to identify the configurations by optical microscopy and elucidate the impact on the vibrational and luminescence characteristics by confocal spectroscopy mapping. In particular, we highlight the increase of intensity and shift due to the photonic properties of nanowires and increase in dielectric screening associated with the GaAs NW. This work signifies the first step towards the use of vertical III-V NW arrays as a versatile platform for spatially engineering the optical properties of TMDs.