학술논문

Optical, dielectric and photocatalytic properties of perovskite ZnTiO3 nanoparticle synthesized by sonochemical process
Document Type
Conference
Source
2015 Joint IEEE International Symposium on the Applications of Ferroelectric (ISAF), International Symposium on Integrated Functionalities (ISIF), and Piezoelectric Force Microscopy Workshop (PFM) Applications of Ferroelectric, International Symposium on Integrated Functionalities and Piezoelectric Force Microscopy Workshop (ISAF/ISIF/PFM), 2015 Joint IEEE International Symposium on the. :280-283 May, 2015
Subject
Components, Circuits, Devices and Systems
Engineered Materials, Dielectrics and Plasmas
Dielectrics
Zinc
Nanoparticles
Powders
Absorption
Temperature
Calcination
ZnTiO3
nanoparticles
sonochemical method
XANES
Language
ISSN
1099-4734
2375-0448
Abstract
The sonochemical method was employed for synthesizing perovskite zinc titanate nanopowders. The yield powders were calcined at 600–900 °C for 2 h. High crystallinity phase of cubic ZnTiO 3 was obtained at calcination temperature of 600 °C while mixing phase of cubic and hexagonal was observed in the sample calcined at 700 °C. For the samples calcined at 800 and 900 °C, the hexagonal structure was dominant phase with a trace of rutile TiO 2 and spinel Zn 2 TiO 4 phase. X-ray absorption near edge spectroscopy technique (XANES) was used to probe crystal and local structure of the synthesized powders. The samples calcined at 700 °C exhibited the superior photocatalytic performance in decolorization of Rhodamine B dye under ultraviolet irradiation within 75 min. The dielectric permittivity and loss tangent of ZnTiO 3 calcined at 700 °C was found to be 20 and