학술논문

Enhanced Dielectric Response and Sensing Performance of Bi2MnCoO6/BaTiO3 Composites for Temperature Sensing Application
Document Type
Periodical
Source
IEEE Transactions on Dielectrics and Electrical Insulation IEEE Trans. Dielect. Electr. Insul. Dielectrics and Electrical Insulation, IEEE Transactions on. 30(4):1663-1670 Aug, 2023
Subject
Fields, Waves and Electromagnetics
Engineered Materials, Dielectrics and Plasmas
Temperature sensors
Dielectrics
Capacitance
Temperature measurement
Temperature distribution
Perovskites
Ceramics
Capacitive temperature sensor
dielectric spectroscopy
diffuse phase transition
double perovskite oxide
electro-ceramics
relaxor ferroelectric (RFE)
Language
ISSN
1070-9878
1558-4135
Abstract
Dielectric ceramics are proven and promising candidates for capacitive temperature sensor application due to their great sensitivity and linearity over a defined temperature range. The sensor is appropriate for applications that require high accuracies in a narrow temperature range, such as biomedicine, food safety, and food processing. In this study, we have synthesized the composites ( $1-{x}{)}$ Bi2MnCoO6-( ${x}{)}$ BaTiO3 consisting of two individual phases where ${x}$ = 0, 0.02, 0.06, and 0.10 were prepared by a solid-state reaction method. The surface morphology of ( $1-{x}{)}$ Bi2MnCoO6-( ${x}{)}$ BaTiO3 ceramics has been studied using field emission scanning electron microscope (FESEM) micrographs and found enhancement in the average grain size with the addition of BaTiO3. The dielectric spectroscopy revealed that as the temperature increases, there is an increase in dielectric constant, and all the samples exhibit frequency-dependent relaxor ferroelectric (RFE) behavior with a broad peak at curie temperature due to diffusive phase transition. There is also a significant increase in the dielectric constant and a decrease in the dielectric loss of ( $1-{x}{)}$ Bi2MnCoO6-( ${x}{)}$ BaTiO3 ceramics observed with an increase in BaTiO3 concentration due to excellent dielectric properties of BaTiO3. As the capacitance is directly proportional to the material’s dielectric constant, there is also an increase in the sensing property of the sensor. From the measured data, the sensitivity of ( $1-{x}{)}$ Bi2MnCoO6-( ${x}{)}$ BaTiO3 composites are 1.21, 3.01, 5.63, and 6.26 pF/°C. Among all the composites, the ${x}$ = 0.10 composite shows the highest sensitivity and linear response in the desired ambient temperature range.