학술논문
Photovoltaic Measurement Under Different Illumination of the Dye-Sensitized Solar Cell With the Photoanode Modified by Fe2O3/g-C3N4/TiO2 Heterogeneous Nanofibers Prepared by Electrospinning With Dual Jets
Document Type
Periodical
Author
Source
IEEE Transactions on Semiconductor Manufacturing IEEE Trans. Semicond. Manufact. Semiconductor Manufacturing, IEEE Transactions on. 36(2):291-297 May, 2023
Subject
Language
ISSN
0894-6507
1558-2345
1558-2345
Abstract
In this study, iron oxide (Fe2O3)/graphitic carbon nitride (g-C3N4)/titanium dioxide (TiO2) nanofibers (NFs) were used as an additional layer on photoanode in dye-sensitized solar cells (DSSCs) to improve the photovoltaic performance of DSSCs. The nanofibers were prepared by electrospinning with double jets. The heterogeneous nanofiber composite mainly includes Fe2O3, g-C3N4, and TiO2. The Fe2O3/g-C3N4/TiO2 NFs were characterized by X-ray diffractometer (XRD), and the surface morphology was observed by a field emission scanning electron microscope (Fe-SEM). The electrochemical impedance spectroscopy (EIS) was applied to analyze the impedance of the cell. The incident photon current efficiency (IPCE) measurements were applied to determine the quantum efficiency, and ultraviolet-visible (UV-Vis) spectrophotometer was applied to observe the dye adsorption and absorption wavelength. To understand the performance of the modified photoanodes in DSSCs, we analyzed the photovoltaic parameters. The results suggest that the addition of Fe2O3/g-C3N4/TiO2 NFs is able to improve the conversion efficiency of the modified DSSCs to 4.81%. In addition, the efficiency under different illumination was also analyzed, and the highest conversion efficiency was 6.81% at 30 mW/cm2.