학술논문

Progress Toward Machine Learning Methodologies for Laser-Induced Breakdown Spectroscopy With an Emphasis on Soil Analysis
Document Type
Periodical
Source
IEEE Transactions on Plasma Science IEEE Trans. Plasma Sci. Plasma Science, IEEE Transactions on. 51(7):1729-1749 Jul, 2023
Subject
Engineered Materials, Dielectrics and Plasmas
Fields, Waves and Electromagnetics
Soil
Spectroscopy
Electric breakdown
Plasmas
Feature extraction
Support vector machines
Soil measurements
Classification
feature extraction
laser-induced breakdown spectroscopy (LIBS)
machine learning (ML)
matrix effect reduction
quantitative analysis
soil analysis
Language
ISSN
0093-3813
1939-9375
Abstract
Optical emission spectroscopy of laser-produced plasmas, commonly known as laser-induced breakdown spectroscopy (LIBS), is an emerging analytical tool for rapid soil analysis. However, specific challenges with LIBS exist, such as matrix effects and quantification issues, which require further study in the application of LIBS, particularly for the analysis of heterogeneous samples, such as soils. Advancements in the applications of machine learning (ML) methods can address some of these issues, advancing the potential for LIBS in soil analysis. This article aims to review the progress of LIBS application combined with ML methods, focusing on methodological approaches used in reducing matrix effect, feature selection, quantification analysis, soil classification, and self-absorption. The performance of various adopted ML approaches is discussed, including their shortcomings and advantages, to provide researchers with a clear picture of the current status of ML applications in LIBS for improving its analytical capability. The challenges and prospects of LIBS development in soil analysis are proposed, offering a path toward future research. This review article emphasizes ML tools for LIBS soil analysis, which are broadly relevant for other LIBS applications.