학술논문

Kinetics of Leaching Calcium from Dolomite
Document Type
article
Source
Kemija u Industriji, Vol 60, Iss 06, Pp 335-342 (2011)
Subject
magnesia
magnesite
kinetics of calcium
dolomite
Chemistry
QD1-999
Language
English
Croatian
ISSN
0022-9830
1334-9090
Abstract
Magnesia is obtained from magnesite ore and the production process applied should remove accompanying minerals that reduce its refractoriness. Given that magnesite reservoirs are more exploited and largely exhausted, there is a growing need for production of magnesia on the basis of other magnesium minerals. Dolomite is a promising source of magnesia because it forms large deposits, is easy to exploit, and generally contains a small quantity of impurities.The kinetics of calcium leaching from dolomite by magnesium-nitrate solution has been studied. The research program included the influence of temperature, mass fraction of magnesium nitrate in solution, dolomite particle size and leaching time. Time dependence of calcium leaching is described by relevant kinetic equations. Rate coefficients, their temperature dependence and Arrhenius activation energy have been determined.