학술논문

CMAS corrosion resistance of YSZ thermal barrier coatings with Al2O3 and YSZ-Al2O3 protective layers
Document Type
Article
Source
In Ceramics International 1 November 2024 50(21) Part C:44401-44416
Subject
Language
ISSN
0272-8842
Abstract
Molten calcium-magnesium-alumina-silicate (CMAS) corrosion has become a major constraint for the application of YSZ thermal barrier coatings (TBCs). In this paper, Al2O3 and YSZ-Al2O3 protective layers with a thickness of 50 μm were prepared on the surface of 8YSZ TBCs using air plasma spraying technology, and the progressive damage modes of the different TBCs under CMAS exposure were investigated, and the effects of the composition and microstructure of the protective layers on the infiltration and wetting behaviour of CMAS were compared. When the exposure time was shorter, the dense YSZ-Al2O3 had a better impermeability barrier effect. As the interaction time between CMAS and the coating was prolonged, the structure and phase stability of YSZ-Al2O3 were damaged, the thickness was thinned, and Al2O3 had better stability and showed better protective effect. CMAS wettability was mainly related to the roughness of the coating surface, and the wettability was poorer on rough surfaces.