부산대학교 도서관

Time-resolved resonance Raman (RR) spectra of the benzyl radical and its perdeutero isotopomer are presented. The radicals are created by laser flash photolysis (λ=266 nm) of benzylchloride in solution. The spectra are excited at a wavelength of 315 nm, in resonance with the intense D3(2 2A2)←D0(1 2B2) transition. Twenty Raman bands, both polarized and depolarized, are observed. The RR spectra are analyzed through quantum chemical force field for π electrons (QCFF/PI) and ab initio calculations of equilibrium geometries, vibrational frequencies, Franck–Condon factors, and vibronic interactions. Polarized intense bands are assigned to totally symmetric a1 modes, and a number of depolarized bands to fundamentals of b1 modes. The observed activity of b1 modes suggests vibronic coupling, which is confirmed theoretically by calculations of vibronic interactions between the D3(2 2A2) and D5(4 2B2) states. The results from semiempirical and ab initio calculations are compared with experiment. The contributions of the different internal coordinates to the normal modes are calculated together with the changes in the molecular structure upon electronic excitation from D0 to D3 and D5. [ABSTRACT FROM AUTHOR]