학술논문

Synthesis of regioisomeric naphtho-furans via naphthyloxyalkanals.
Document Type
Article
Source
Chemistry of Heterocyclic Compounds. Jan2010, Vol. 46 Issue 1, p20-29. 10p. 5 Diagrams, 5 Charts.
Subject
*ALDEHYDES
*HETEROCYCLIC compounds
*ETHERS
*CHLORIDES
*RING formation (Chemistry)
*CHLORINE compounds
Language
ISSN
0009-3122
Abstract
A new route to the regioisomeric 2-alkylnaphtho[2,1-b]- and 2-alkylnaphtho[1,2-b]furans via acid-catalyzed cyclization of the corresponding 2-naphthyloxyalkanals under mild conditions over Amberlyst 15 resin has been described. The 2-naphthyloxyalkanals were obtained by palladium-catalyzed reduction of 2-naphthyloxyalkanoyl chlorides. [ABSTRACT FROM AUTHOR]