학술논문
Synthesis of η1-borazine complexes of palladium and platinum.
Document Type
Article
Source
Subject
*MATHEMATICAL transformations
*LINEAR algebra
*LINE geometry
*MATHEMATICAL complexes
*
*
*
Language
ISSN
1477-9226
Abstract
The η1-borazine complexes trans-[(Cy3P)2M(Br)(Br2B3N3H3)] (Cy = cyclohexyl) were prepared by oxidative additon of a B–Br bond of (BrBNH)3 to [M(PCy3)2] (M = Pd, Pt). Furthermore the platinum compound was converted into the T-shaped cationic complex trans-[(Cy3P)2Pt(Br2B3N3H3)][BArf4] [Arf = 3,5-(CF3)2C6H3] by addition of Na[BArf4]. [ABSTRACT FROM AUTHOR]