학술논문

Redox-neutral zinc-catalyzed cascade [1,4]-H shift/annulation of diaziridines with donor–acceptor aziridines.
Document Type
Article
Source
Chemical Communications. 3/28/2024, Vol. 60 Issue 25, p3441-3444. 4p.
Subject
*DIAZIRINES
*AZIRIDINES
*ANNULATION
*MOLECULAR docking
*NATURAL products
Language
ISSN
1359-7345
Abstract
The coupling of diaziridines with donor–acceptor aziridines (DAAs) has been achieved using Zn-catalysis to furnish imidazopyrazole-4,4-dicarboxylates via [1,4]-hydride shift. The use of Zn-catalysis, [1,4]-hydride shift, natural product modification and a late-stage molecular docking study are important practical features. [ABSTRACT FROM AUTHOR]