학술논문

Kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cages.
Document Type
Article
Source
Chemical Communications. 12/7/2023, Vol. 59 Issue 94, p13974-13977. 4p.
Subject
*PORPHYRINS
*CHIRALITY
*SPECTROMETRY
*ION mobility spectroscopy
*METALLOPORPHYRINS
*IONS
*GAS hydrates
Language
ISSN
1359-7345
Abstract
The kinetic enantio-recognition of chiral viologen guests by planar-chiral porphyrin cage compounds, measured in terms of ΔΔG ‡on , is determined by the planar-chirality of the host and influenced by the size, as measured by ion mobility-mass spectrometry, but not the chirality of its substituents. [ABSTRACT FROM AUTHOR]