학술논문

Enhanced Electrochemical Performance of Sugarcane Bagasse-Derived Activated Carbon via a High-Energy Ball Milling Treatment.
Document Type
Article
Source
Nanomaterials (2079-4991). Oct2022, Vol. 12 Issue 20, p3555-N.PAG. 17p.
Subject
*ACTIVATED carbon
*BAGASSE
*BALL mills
*SUGARCANE
*ENERGY density
*ACTIVATION (Chemistry)
*ELECTRIC capacity
*SUPERCAPACITOR electrodes
Language
ISSN
2079-4991
Abstract
Activated carbon (AC) from sugarcane bagasse was prepared using dry chemical activation with KOH. It was then subjected to a high-energy ball milling (HEBM) treatment under various milling speeds (600, 1200 and 1800 rpm) to produce AC nanoparticles from micro-size particles. The AC samples after the HEBM treatment exhibited reduced particle sizes, increased mesopore volume and a rich surface oxygen content, which contribute to higher pseudocapacitance. Notably, different HEBM speeds were used to find a good electrochemical performance. As a result, the AC/BM12 material, subjected to HEBM at 1200 rpm for 30 min, exhibited the highest specific capacitance, 257 F g−1, at a current density 0.5 A g−1. This is about 2.4 times higher than that of the AC sample. Moreover, the excellence capacitance retention of this sample was 93.5% after a 3000-cycle test at a current density of 5 A g−1. Remarkably, a coin cell electrode assembly was fabricated using the AC/BM12 material in a 1 M LiPF6 electrolyte. It exhibited a specific capacitance of 110 F g−1 with a high energy density of 27.9 W h kg−1. [ABSTRACT FROM AUTHOR]