학술논문
New insights into the selective and systematic preparation of arylgermanium hydrides.
Document Type
Article
Source
Subject
*NUCLEAR magnetic resonance spectroscopy
*SINGLE crystals
*GERMANIUM
*ORGANOGERMANIUM compounds
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Language
ISSN
0959-9436
Abstract
[Display omitted] A series of novel arylgermanium hydrides Ar n GeH 4 –n (n = 1–3) and diaryl(chloro)germanium hydrides Ar 2 Ge(Cl)H were synthesized and characterized. Systematic preparation and purification were achieved via the lithium chloride–triflic acid and the optimized Grignard route. Arylgermanium hydrides Ar n GeH 4– n (Ar = 2,5-Me 2 C 6 H 3 , n = 1–3) were characterized by 1H and 73Ge NMR spectroscopy and single crystal X-ray diffractometry. [ABSTRACT FROM AUTHOR]