학술논문
Photoreductive chlorine elimination from a Ni(III)Cl2 complex supported by a tetradentate pyridinophane ligand.
Document Type
Article
Source
Subject
*ELIMINATION reactions
*CHLORINE
*IRRADIATION
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Language
ISSN
1359-7345
Abstract
Herein we report the isolation, characterization, and photoreactivity of a stable NiIII dichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the NiIIICl2 species can be regenerated via a reaction with PhICl2. [ABSTRACT FROM AUTHOR]