학술논문

Synthesis of 6-methyl-2-[2-phenyl-2-(arylhydrazono)ethyl]-3 Н-pyrimidine-4-ones and their oxidation by hydrogen peroxide and selenium dioxide.
Document Type
Article
Source
Russian Journal of General Chemistry. Jul2016, Vol. 86 Issue 7, p1604-1607. 4p. 2 Diagrams.
Subject
*PHENYL compounds
*PHENYL group
*PYRIMIDINE synthesis
*HYDRAZINES
*ETHYLENE
Language
ISSN
1070-3632
Abstract
The reaction of 6-methyl-2-(2-oxo-2-phenylethylidene)-2,3-dihydropyrimidine-4(1 H)-one with arylhydrazines leads in high yields to the corresponding hydrazones, in which the ethylidene fragment of the starting compound is transformed to the ethylene fragment. By oxidation of the hydrazones with hydrogen peroxide or selenium dioxide the corresponding 6-methyl-2-[2-phenyl-2-(arylhydrazono)acetyl]-3 H-pyrimidine-4-ones were synthesized. [ABSTRACT FROM AUTHOR]