학술논문

Direct observation of the non-supported metal nanoparticle electron density of states by X-ray photoelectron spectroscopy
Document Type
Source
European Physical Journal D. 45(2):295-299
Subject
73.22.-f Electronic structure of nanoscale materials: clusters
nanoparticles
nanotubes
and nanocrystals - 79.60.-i Photoemission and photoelectron spectra
NATURAL SCIENCES
Physics
NATURVETENSKAP
Fysik
Language
English
ISSN
1434-6060
1434-6079
Abstract
Synchrotron-based X-ray photoelectron spectroscopy on copper and silver cluster beams created by a magnetron-based gas-aggregation source has allowed mapping the electron density of states (DOS) of free metallic nanoparticles. The cluster DOS profiles obtained in the experiments strongly resemble the infinite solid DOS shapes, but the extracted cluster work-functions are lower than those for the bulk metal. The latter observation is explained by the initial negative charge on most of the clusters, created by the source.