학술논문
Probing RbBr solvation in freestanding sub-2 nm water clusters
Document Type
Author
Source
Physical Chemistry Chemical Physics. 19(36):25158-25167
Subject
Language
English
ISSN
1463-9076
Abstract
Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg-1. For comparison, spectra from anhydrous RbBr clusters are also presented.