학술논문

Electron exchange-correlation in quantum mechanics
Document Type
Journal Article
Author
Source
International Journal of Quantum Chemistry, vol. 111, n/a, January 1, 2011, pp. 1; 111; 1
Subject
74 ATOMIC AND MOLECULAR PHYSICS BOUND STATE
ELECTRONS
FERMI STATISTICS
MAGNETIC MOMENTS
PAULI PRINCIPLE
QUANTUM MECHANICS
TRAJECTORIES
VELOCITY
Language
English
ISSN
0020-7608
Abstract
It is shown that Fermi-Dirac statistics is guaranteed by the Dirac current, from which spin-dependent quantum velocity fields and spin-dependent quantum trajectories can be inferred. Pauli's exclusion principle is demonstrated using the spin-dependent quantum trajectories. The Dirac current, unlike the Schroedinger current, is nonzero for stationary bound states due to the permanent magnetic moment of the electron. It is of order c{sup 0} in agreement with observation that Fermi-Dirac statistics is independent of electronic velocity. In summary the physical basis for exchange-correlation is found in Dirac's equation, although Schroedinger's equation may be used to evaluate the Dirac current in the nonrelativistic regime of electronic velocity.