학술논문

Calculation of dissociative ionization cross sections of diatomic molecules
Document Type
Journal Article
Author
Source
Phys. Rev., A, v. 12, no. 5, pp. 1872-1880; Other Information: Orig. Receipt Date: 30-JUN-76
Subject
N60200* --Physics (Atomic & Molecular)--Atomic & Molecular Properties
N60400 --Physics (Atomic & Molecular)--Collision Phenomena
640302* --Physics Research--Atomic, Molecular & Chemical Physics--Atomic & Molecular Properties ELECTRONS-- EV RANGE 100-1000
IONIZATION CARBON MONOXIDE-- HYDROGEN-- MOLECULES-- NITROGEN-- NITROGEN OXIDES-- OXYGEN
Language
English
Abstract
A model for calculating the dissociative ionization cross sections of diatomic molecules is developed. The activated state for dissociative ionizations is modeled to occur via the ejection of a bound electron and an excitation of another bound electron. This process is described by successive two-electron scattering in the first Born and the binary-encounter approximations. Comparison of calculated cross sections with available experimental data for five diatomic molecules (H$sub 2$, CO, N$sub 2$, NO, and O$sub 2$) shows good agreement with incident-electron energies above 200 eV. (AIP)