학술논문

PROGRESS REPORT ON SOLID STATE POLYMERIZATION INITIATED BY GAMMA RADIATION
Document Type
Technical Report
Author
Source
Other Information: Orig. Receipt Date: 31-DEC-61
Subject
CHEMISTRY ACRYLIC ACID
AIR
ALKALINE EARTH METALS
COBALT 60
CRYSTALLIZATION
GAMMA RADIATION
LITHIUM
METHACRYLIC ACID
MOLECULES
ORGANIC ACIDS
POLYMERIZATION
POLYMERS
POTASSIUM
PREPARATION
RADIATIONS
REACTION KINETICS
SALTS
SODIUM
SOLIDS
STEARIC ACID
TEMPERATURE
VINYL RADICALS
WEIGHT
Language
English
Abstract
The kinetics of the polymerization of potassium, sodium, and lithium salts of acrylic acid exposed at - 78 ts C to radiation from a Co/ sup 60/ source was studied over a range of temperatures, following both the yield and the molecular weight of the polymer as a function of time. A number of alkalineearth salts of acrylic or methacrylic acid were prepared in the anhydrous or various hydrated forms. The polymerizability of these materials sealed under air and exposed to a dose of 800,000 rads at -- 28 ts C is given. Polymerization kinetics of vinyl stearate purified by repeated recrystallization was studied. (W.L.H.)