학술논문

Calendar and PHEV Cycle Life Aging of High-Energy, Lithium-Ion Cells Containing Blended Spinel and Layered Oxide Cathodes
Document Type
Journal Article
Author
Source
Journal of Power Sources; 196; 23
Subject
25 ENERGY STORAGE AGING
CALENDARS
CATHODES
KINETICS
OXIDES
PERFORMANCE
SPINELS
LITHIUM IONS Lithium Ion Battery
Lithium Ion Battery
Language
English
ISSN
0378-7753
Abstract
One hundred seven commercially available, off-the-shelf, 1.2-Ah cells were tested for calendar life and CS cycle- and CD cycle-life using the new USABC PHEV Battery Test Manual. Here, the effects of temperature on calendar life, on CS cycle life, and on CD cycle life; the effects of SOC on calendar life and on CS cycle life; and the effects of rest time on CD cycle life were investigated. The results indicated that the test procedures caused performance decline in the cells in an expected manner, calendar < CS cycling < CD cycling. In some cases, the kinetic law changed with test type, from linear-with-time to about t2. Additionally, temperature was found to stress the cells more than SOC, causing increased changes in performance with increasing temperature.