학술논문

Isotope effects in the metastable decay of Ne2 +
Document Type
Original Paper
Source
The European Physical Journal D: Atomic, Molecular, Optical and Plasma Physics. 07 2007 43(1-3):77-80
Subject
36.40.Qv Stability and fragmentation of clusters
36.40.Wa Charged clusters
33.15.Hp Barrier heights (internal rotation, inversion, rotational isomerism, conformational dynamics)
34.30.+h Intramolecular energy transfer; intramolecular dynamics; dynamics of van der Waals molecules
Language
English
ISSN
1434-6060
1434-6079
Abstract
Abstract.:Neon dimer ions undergo spontaneous dissociation (metastable decay) severalmicroseconds after formation by electron impact ionization of neon clusters.In this contribution we compare the kinetic energy release distribution(KERD) of the previously reported isotopomer 20Ne2+ with thatof 22Ne2+. The heavy isotopomer shows the same two componentsin the KERD as the lighter ones. However, the high-energy component that isdue to electronic pre-dissociation is reduced in intensity. The decrease isattributed to a reduced predissociation rate from the II(1/2u) state intoI(3/2u).