학술논문
Analyzing the effects of thermal stress on insulator papers by solid-state 13 C NMR spectroscopy
Document Type
Original Paper
Author
Source
Cellulose. 29(2):1081-1095
Subject
Language
English
ISSN
0969-0239
1572-882X
1572-882X
Abstract
Million tons of cellulosic paper have been used for insulating coils in oil-filled electrical power transformers, thereby assuring the electricity supply for our societies. The high working temperatures in transformers constantly degrade paper insulators throughout their service life of up to 40 years. We approached the structural changes in oil-immersed cellulosic paper samples upon thermal stress in a study that compared unbleached softwood Kraft paper used as insulator paper with pure cotton cellulose paper. The model experiments used a thermal treatment in transformer oil at 170 °C for up to 14 days. The samples were characterized by means of 13 C CP/MAS NMR spectroscopy, mainly based on deconvolution of the C4 resonance. An automated, fast, and reproducible C4 resonance deconvolution employing the “Peak Analyzer” tool of OriginPro 2020 (OriginLab Corporation, USA) was developed and used to exploit 13 C CP/MAS NMR spectroscopy for the characterization of thermally stressed paper samples. Our results show that thermally induced structural changes depend heavily on the composition of paper, that hornification and coalescence of fibrils take place, and that the allomorph composition of cellulose crystallites is altered under the given conditions.Graphical abstract: