학술논문

Characterisation of Siccative Oils, Resins and Pigments in Art Works by Thermochemolysis Coupled to Thermal Desorption and Pyrolysis GC and GC-MS
Document Type
Original Paper
Source
Chromatographia. 02 2004 59(3-4):227-231
Subject
Gas Chromatography-mass spectrometry Thermal desorption Pyrolysis Oil and resins Tetramethylammonium hydroxide
Language
English
ISSN
0009-5893
1612-1112
Abstract
Thermal desorption in the presence of tetramethylammonium hydroxide (TMAH) has been applied to materials belonging to the artistic field to verify the effectiveness of the derivatisation reaction. Thermal desorption of siccative oils and abietane resins give consistent results with traditional pyrolysis in methylation conditions, while as regard antraquinonic dyes the milder thermal treatment leads to the formation of more diagnostic compounds than pyrolysis.