부산대학교 도서관

The effect of aging on the mechanical properties of silicone rubber (SR) was investigated by means of ultrasonic, dynamic mechanical analysis, and FTIR techniques. Both longitudinal and shear (Ultrasonic wave velocities) were measured at room temperature and at frequencies of 2 MHz. Density, molar volume, ultrasonic wave velocities, tensile strength, mechanical properties, and FT–IR showed the improvement of the silicone rubber network with aging time from 0 to 70 days, while loosening of the network structure was observed at 14 days and 50 days aging. These behaviours were explained in terms of the change in cross-link density and average stretching force constant of bonds with aging. Thermogravimetric analysis and differential scanning calorimetric techniques showed quite low thermal stability and temperature performance for aged SR at 14 and 50 days than virgin SR which was confirmed by the cracks and voids appeared under scanning electron microscope.