학술논문
Protonated diamines as linkers in the supramolecular assemblies based on the [V12 B18 O60 H6 ] polyoxovanadoborate anion
Document Type
Original Paper
Author
Source
Journal of Structural Chemistry. December 2014 55(8):1453-1465
Subject
Language
English
ISSN
0022-4766
1573-8779
1573-8779
Abstract
Two new polyoxovanadoborates based crystalline lattices are being reported: K5 (H3 O)2 (1,3-diapH2 )2 [V12 B18 O60 H6 ]·10.80H2 O (1), and K2 (H3 O)7 (enH2 )[V12 B18 O60 H6 ]·9H2 O (2). These structures are characterized by presenting multiple hydrogen bonds between the diprotonated diamines (enH2 and 1,3-diapH2 ) and hydronium ions, and the oxygen atoms of the [V12 B18 O60 H6 ] cluster. The crystalline packing and stability of these new polyoxovanadoborates is dominated by the different types of hydrogen interactions present in the lattices ranging from unidirectional to trifurcated ones. The crystallographic data, together with the BVS method, permit to assign a mixed valence ratios for the [V12 B18 O60 H6 ] anionic cluster for (1) and (2) being 11/1 (VIV /VV ) ratio.