학술논문

Sorption behavior of fission products (Tc, I) in marine and freshwater bottom sediments
Document Type
Original Paper
Source
Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry. 333(4):1963-1973
Subject
Bottom sediments
Technetium
Iodine
Sapropel
Sorption behavior
Language
English
ISSN
0236-5731
1588-2780
Abstract
The study investigated the sorption behaviour of 99Tc and 125I on bottom sediments from the Japan Sea, Khanka Lake and commercially available sapropel. It was determined that organic matter can have an impact on the iodine sorption process. After a 20-day period, sapropel reached an equilibrium state with a sorption value of up to 100%. In real systems of bottom sediment–water in the Far East region, iodine sorption was found to be superior on marine bottom sediments with a sorption value reaching 85% within 20 days, as opposed to freshwater sediments which only reached up to 35% within the same period. Tc(VII) in the form of pertechnetate anion exhibits no sorption under either aerobic or anaerobic conditions in the pH range of 4–11. Under aerobic conditions at pH 11 Tc(IV) is sorbed up to 15% only on sapropel; under anaerobic conditions at pH 7 the sorption reaches 25% for lake sediments, 10% for marine sediments and when the pH is 11, the sorption value of Tc by sapropel is as high as 100%.