학술논문
P4 activation by lanthanum and lutetium naphthalene complexes supported by a ferrocene diamide ligand
Document Type
article
Author
Source
European Journal of Inorganic Chemistry. 2013(22-23)
Subject
Language
Abstract
Two rare-earth (La and Lu) naphthalene complexes supported by a ferrocene diamide ligand activate P4 under ambient conditions to form M 3P7 species exclusively. The resulting complexes feature a Zintl-type polyphosphide P73- unit stabilized by three lanthanide fragments. The reported metal complexes were characterized by X-ray crystallography, multinuclear NMR spectroscopy, and elemental analysis. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.