학술논문

Conductive Polymer Binder-Enabled SiO-SnxCoyCz Anode for High-Energy Lithium-Ion Batteries.
Document Type
article
Source
ACS applied materials & interfaces. 8(21)
Subject
conductive polymer binder
high capacity anode
lithium-ion battery
practical application
prelithiation
Nanoscience & Nanotechnology
Chemical Engineering
Macromolecular and Materials Chemistry
Physical Chemistry
Chemical Sciences
Engineering
Language
Abstract
A SiOSnCoC composite anode is assembled using a conductive polymer binder for the application in next-generation high energy density lithium-ion batteries. A specific capacity of 700 mAh/g is achieved at a 1C (900 mA/g) rate. A high active material loading anode with an areal capacity of 3.5 mAh/cm(2) is demonstrated by mixing SiOSnCoC with graphite. To compensate for the lithium loss in the first cycle, stabilized lithium metal powder (SLMP) is used for prelithiation; when paired with a commercial cathode, a stable full cell cycling performance with a 86% first cycle efficiency is realized. By achieving these important metrics toward a practical application, this conductive polymer binder/SiOSnCoC anode system presents great promise to enable the next generation of high-energy lithium-ion batteries.