학술논문
Compression of a Stearic Acid Surfactant Layer on Water Investigated by Ambient Pressure X‑ray Photoelectron Spectroscopy
Document Type
article
Author
Source
The Journal of Physical Chemistry B. 128(15)
Subject
Language
Abstract
We present a combined Langmuir-Pockels trough and ambient pressure X-ray photoelectron spectroscopy (APXPS) study of the compression of stearic acid surfactant layers on neat water. Changes in the packing density of the molecules are directly determined from C 1s and O 1s APXPS data. The experimental data are fit with a 2D model for the stearic acid coverage. Based on the results of these proof-of-principle experiments, we discuss the remaining challenges that need to be overcome for future investigations of the role of surfactants in heterogeneous chemical reactions at liquid-vapor interfaces in combined Langmuir-Pockels trough and APXPS measurements.