학술논문

2-7[{3-(Triethoxysilyl)propyl}amino]pyridine and Derivatives
Document Type
Academic Journal
Source
Russian Journal of General Chemistry. Dec 01, 2001 71(12):1879-1882
Subject
Language
English
ISSN
1070-3632
Abstract
2-{[3-(Triethoxysilyl)propyl]amino}pyridine is synthesized by condensation of [3-(triethoxysilyl)propyl]amine with 2-aminopyridine. Its peretherification with triethanolamine leads to 2-[(3-silatranylpropyl)amino]pyridine and hydrolytic copolycondensation with tetraethoxysilane to cross-linked organosilicon copolymer {SiO2·2[O1.5Si(CH2)3NHC6H4N]}n. The latter in the medium of hydrochloric acid behaves as an anionite in respect of anionic chlorocomplexes of gold(III), platinum(IV), palladium(II) and rhodiumIII).