학술논문

Facile electrosynthesis of Fe (Ni/Co) hydroxyphosphate as a bifunctional electrocatalyst for efficient water splitting
Document Type
Article
Source
Journal of Industrial and Engineering Chemistry, 70(0), pp.116-123 Feb, 2019
Subject
화학공학
Language
English
ISSN
1876-794X
1226-086X
Abstract
Porous iron–nickel hydroxyphosphate and iron–cobalt hydroxyphosphate electrodes are prepared byone-step electrodeposition method. The as-prepared iron–nickel hydroxyphosphate and iron–cobalthydroxyphosphate electrodes show excellent performance for water splitting with high catalytic activitytowards the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), with a loweroverpotential of 220 and 235 mV for the OER and 145 and 160 mV for the HER, respectively. Moreover,two-electrode electrolyzer using iron-nickel hydroxyphosphate as both the anode and cathode requires acell voltage of 1.65 V while iron–cobalt hydroxyphosphate requires cell voltage of 1.67 V to gain currentdensity of 10 mA cm 2.