부산대학교 도서관

Aluminum (Al) alloys are used in a wide range of applications due to their advantages. However, theexisting corrosion protection methods have insufficient protection ability and cannot achieve longtermprotection. In this paper, reactive protective film on the surface of aluminum alloys using 1-hydroxyethyl-1,1-diphosphonic acid (HEDP) molecules. Then, Lauric acid/Graphene (LA/rGO) film is usedto prepared on the surface of HEDP film. SEM, XRD, EDS, Raman, XPS and WCA were conducted to analyzephysical and chemical features of coatings. The total resistance of the film reaches 1.0 1020 Xcm2, in asalt spray test using 5wt% NaCl as the corrosion medium, corrosion spots appeared on day 28 with a corrosioninhibition efficiency of 99.99%. Theoretical studies with quantum chemical calculations haveshown that HEDP/LA/rGO composite films can be adsorbed on Al alloy surfaces through P-O-Al and PO-C chemical bonding. The influence of phosphate synergistic effect on the corrosion resistance of theself-assembled superhydrophobic composite film on the surface of 6061 aluminum alloy is discussed. This study presents a scientific and innovative design concept to develop coatings with excellent corrosionprotection for aluminum alloy, and then extend their application to certain areas.