학술논문
Synthesis of thiatriphyrin analogues and physical properties / チアトリフィリン類縁体の合成と物性
Document Type
Journal Article
Author
Source
Abstracts of Symposium on Physical Organic Chemistry. 2011, :146
Subject
Language
Japanese
Abstract
Our group has been elaborating [14]triphyrins(2.1.1) by using Lindsey method or McMurry coupling method. However triphyrins with thiophene skeleton have not been reported until now. Therefore in this work, one of pyrroles of triphyrin had been changed to thiophene and formylated, then cyclized by McMurry coupling method to get thiatriphyrin. However we got thiatriphyrin analogues that was nonaromatic. The synthesis and photophysical properties of the products were investigated.