학술논문

INVESTIGATION INTO WATER UPTAKE CHARACTERISTICS OF HARDENED CEMENT PASTE BASED ON DIFFUSION EQUATION / 拡散方程式に基づいたセメント硬化体への水分浸透特性の検討
Document Type
Journal Article
Source
セメント・コンクリート論文集 / Cement Science and Concrete Technology. 2023, 76(1):290
Subject
Capillary pores
Diffusion equation
Diffusivity
Fourth root of uptake time
Gel pores
Water uptake
ゲル空隙
拡散係数
拡散方程式
毛細管空隙
水分浸透
浸透時間の4乗根
Language
Japanese
ISSN
0916-3182
2187-3313
Abstract
The previous studies have reported that the water absorption amount with time can be proportional to the fourth root of absorption time. In this study, the water uptake characteristics of hardened cement paste was studied from a viewpoint of fourth root of uptake time. The one bottom surface of cement paste specimen was exposed to liquid water after drying equilibrium at 20, 40 and 105℃. The amount of water absorption was proportional to the fourth root of time as reported in the previous studies. In the case of drying at 105℃, the relationship was bilinear, which suggests that the water can penetrate into relatively large capillary pores and then fine gel pores as two processes. The model to apply different diffusion equations to the assumed capillary and gel pores can reproduce the water uptake behavior of cement paste dried at 105℃ when the constant diffusivities are used for each pore. The diffusion equations were applied to divided pore diameters, respectively when the simple pore distribution was assumed. It was found that the model to use constant large and small diffusivities according to threshold of pore diameter can represent the bilinear relationship between the water absorption amount and fourth root of time rather than the model to use the decreasing diffusivity with decreasing pore diameter.