학술논문

Characteristics of the initial activation of a nano-TiFe hydrogen storage alloy prepared by mechanical alloying
Document Type
Journal Article
Source
Journal of Advanced Science. 2004, 16(2):46
Subject
Amorphous
Mechanical alloying
Nanostructure
TiFe
Language
English
ISSN
0915-5651
1881-3917
Abstract
The intermetallic TiFe alloy is a hydrogen storage alloy with a high hydrogen storage capacity, 1.8wt%, and a relatively low cost compared with other alloys. However, the TiFe alloy does not easily start to absorb hydrogen because of the presence of a very stable oxide layers covering the alloy surface. In order to activate the alloy, the alloy needs an intensive initial activation process at high temperatures over 720K under high hydrogen pressures over 6.5MPa. In this study, the intermetallic TiFe alloy was successfully prepared by mechanical alloying of Ti and Fe metals. The formed nano-TiFe alloy with a mixture of nano and amorphous structures was found to have a very easy, activation behavior compared with a standard polycrystalline TiFe alloy.