학술논문

Inclusion Function of Rayon Fibers Containing β-Cyclodextrin / β-シクロデキストリンを添加したレーヨン繊維の包接機能
Document Type
Journal Article
Source
繊維製品消費科学 / JOURNAL of the JAPAN RESEARCH ASSOCIATION for TEXTILE END-USES. 2023, 64(10):623
Subject
ammonia gas
gas adsorption
inclusion function
phenolphthalein
rayon
β-cyclodextrin
β-シクロデキストリン
アンモニアガス
ガス吸着
フェノールフタレイン
レーヨン
包接機能
Language
Japanese
ISSN
0037-2072
1884-6599
Abstract
In a wet spinning process, β-cyclodextrin powder was added to the viscose raw material to produce rayon fibers (hereinafter referred to as “β-CD rayon fibers”). The inclusion function of the β-CD rayon fibers was investigated by dropping a phenolphthalein solution, focusing on the changes in the hue. The inclusion of phenolphthalein molecules in CD increased over time and was the best after one–two days. The effect of heating on the inclusion function of the β-CD rayon fibers was also investigated. It was found that the phenolphthalein molecules included in CD were desorbed by heating at 50°C or higher, but included again when cooled to room temperature. The β-CD rayon fibers were exposed to saturated ammonia gas for 3 h to investigate gas adsorption. The fibers were then left in pure air. After 12 days, the fibers were placed in a new Tedlar® bag, to which pure air was reinjected; the Tedlar® bag containing the fibers was heated at 100°C for 30 min. As a result, the β-CD rayon fibers released a large amount of ammonia gas.