학술논문

Cation ordering in welinite crystals from the Yamada mine, Mie Prefecture, Japan / 三重県山田鉱山産ウエリン石の長周期構造
Document Type
Journal Article
Source
Abstracts for Annual Meeting of Japan Association of Mineralogical Sciences. 2018, :34
Subject
cation ordering
silicate
superstructure
welinite
ウエリン石
ケイ酸塩
超構造
陽イオン秩序配列
Language
Japanese
Abstract
We found welinite from Yamada mine, Mie Prefecture, Japan. Welinite was originally discovered from Langban, Sweden, and its crystal structure was solved in P63or its sub-group P3 with a = 8.155 and c = 4.785 A, and an ideal formula of Mn2+6(W6+,Mg)2(SiO4)2(O,OH)6. On the other hand, the welinite crystals from Yamada mine have a √3 × 3 superstructure with a = 14.074(3) and c = 14.455(3) A, and space group R3. The long-rangeordering of W sites and vacancies causes the superstructure.

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