학술논문
Excited state competition in fac-(Re(super I)(dppz)(CO)3(py-PTZ))(super +)
Document Type
Academic Journal
Source
Journal of Physical Chemistry A. July 8, 1999, Vol. 103 Issue 27, p5227, 5 p.
Subject
Language
ISSN
1089-5639
Abstract
Spectroscopic measurements were done to examine the competition between the electron and energy transfer in fac-(Re(super I)(dppz)-(CO)3(py-PTZ))(super +), where dppz is dipyrido(3,2-a:2'3'-c)phenazine. It has been observed that bands rise on the low energy side of the absorption manifold due to the overlapping metal-to-ligand charge transfer and pi-->pi(super *) transitions. It has also been noted that the pipi(super *) state is the minor product in the competition.