부산대학교 도서관

To link to full-text access for this article, visit this link: http://dx.doi.org/10.1016/S0167-7322(00)00133-1 Byline: Cezary M. Kinart (a), Wojciech J. Kinart (b), Andrzej KolasiAski (a), Aneta AwikliAska (a), Tomasz Dzikowski (c) Abstract: The.sup.1H-NMR spectra of liquid binary mixtures of acetonitrile and propan-1-ol, were recorded at 298 K over almost the whole range of the mixed solvent compositions. From these data were found the values of the spectral parameter, [DELTA][delta](ACNPrOH). The densities (d.sub.12) and relative permittivities (E.sub.12) of the mixed solvent were measured at 288.15 K, 293.15 K, 298.15 K, 303.15 K and 308.15 K, as well as refractive indices at 298.15 K. From all these data, the molar volumes (V.sub.m), apparent molar volumes (V.sub.,i), partial molar volumes (V.sub.i.sup.0), temperature coefficients of relative permittivities ([alpha].sub.12) and their deviations from ideality were calculated. Additionally, the Kirkwood's correlation factors (g.sub.[kappa]) were found. The values of these properties are discussed in terms of interactions of acetonitrile with propan-1-ol. Author Affiliation: (a) University of AodA*, Faculty of Physics and Chemistry, PL 90-236 AodA*, Pomorska 163, Poland (b) University of AodA*, Department of Organic Chemistry, PL 90-136 AodA*, Narutowicza 68, Poland (c) University of AodA*, Department of Nuclear Physics, PL 90-236 AodA*, Pomorska 149/153, Poland